Title: Synthesis of iron-doped zinc oxide nanoparticles by simple heating: influence of precursor composition and temperature
Authors: Sampa Chakrabarti; Xin Liu; Changning Li; Prantik Banerjee; Saikat Maitra; Mark T. Swihart
Addresses: Department of Chemical Engineering, 92, Acharya P.C. Road, Kolkata 700 009, India; Centre for Research in Nanoscience & Nanotechnology, University of Calcutta, India ' Department of Chemical and Biological Engineering, University at Buffalo (SUNY), 310 Furnas Hall, Buffalo, New York, 14260-4200, USA ' Department of Chemical and Biological Engineering, University at Buffalo (SUNY), 310 Furnas Hall, Buffalo, New York, 14260-4200, USA ' Department of Environmental Science, University of Calcutta, 35 Ballygunge Circular Road, Kolkata – 700 029, India ' Government College of Engineering and Ceramic Technology, 73, Abinash Chandra Banerjee Lane, Kolkata – 700 010, India ' Department of Chemical and Biological Engineering, University at Buffalo (SUNY), 310 Furnas Hall, Buffalo, New York, 14260-4200, USA
Abstract: We demonstrate a general single-pot heating method for preparing iron-doped zinc oxide nanocrystals from acetyl acetonate precursors in non-aqueous solvents. The particles were characterised by transmission electron microscopy (TEM), powder X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX), UV-visible (UV-Vis) and Fourier transform infrared (FTIR) optical absorbance spectroscopies. The dependences of the size of the nanocrystals and doping level on the synthesis temperature and precursor composition were elucidated and modelled.
Keywords: crystal structure; nanostructures; semiconductors; chemical synthesis; X-ray diffraction; iron doping; zinc oxide; ZnO nanoparticles; single-pot heating; precursor composition; temperature; nanotechnology; nanocrystals; acetyl acetonate precursors; modelling.
DOI: 10.1504/IJMATEI.2015.069798
International Journal of Materials Engineering Innovation, 2015 Vol.6 No.1, pp.18 - 31
Received: 02 Jan 2014
Accepted: 06 Mar 2014
Published online: 12 Jun 2015 *